Title

An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions

Abstract

Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH2][Co3.5(PO4)3] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.

Department(s)

Chemistry

Keywords and Phrases

cobalt complex; phosphate, article; chemical bond; chemical structure; conformational transition; magnetism; structure analysis; synthesis; temperature; Cobalt; Magnetic properties; Solid-state structures

International Standard Serial Number (ISSN)

1433-7851

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 Wiley-VCH Verlag, All rights reserved.


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