An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions
Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(n) phosphate of the composition [enH2][Co3.5(PO4)3] (en=ethy) lenediamine), the structure of which contains 12-membered channels. In the presence of a magnetic field, the compound undergoes a. transition between two ferrimagnetic states.
A. Choudhury et al., "An Unusual Open-Framework Cobalt(II) Phosphate with a Channel Structure that Exhibits Structural and Magnetic Transitions," Angewandte Chemie International Edition, vol. 39, no. 17, pp. 3091-3093, Wiley-VCH Verlag, Sep 2000.
The definitive version is available at http://dx.doi.org/10.1002/1521-3773(20000901)39:17<3091::AID-ANIE3091>3.0.CO;2-6
Keywords and Phrases
Cobalt Complex; Phosphate, Article; Chemical Bond; Chemical Structure; Conformational Transition; Magnetism; Structure Analysis; Synthesis; Temperature; Cobalt; Magnetic Properties; Solid-State Structures
International Standard Serial Number (ISSN)
Article - Journal
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