Title

An Unusual Open-framework Cobalt(II) Phosphate with a Channel Structure That Exhibits Structural and Magnetic Transitions

Abstract

Magnetic and structural transitions at low temperatures are exhibited by the novel open-framework cobalt(II) phosphate of the composition [enH2][Co3.5(PO4)3] (en=ethylenediamine), the structure of which contains 12-membered channels (see picture). in the presence of a magnetic field, the compound undergoes a transition between two ferrimagnetic states.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2000 Wiley-VCH Verlag, All rights reserved.


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