Thermoelectric Properties of the Tetradymite-Type Bi₂Te₂S-Sb₂Te₂S Solid Solution
The thermoelectric properties of the tetradymite-type Bi2-xSbxTe2S solid solution (0 ≤ x ≤ 2) are reported for the temperature range 5-300 K. The properties of non-stoichiometric, Cl and Sn doped n- and p-type variants are reported as well. The Seebeck coefficients for these materials range from -170 to +270 μV K-1 while the resistivities range from those of semimetals, 2 mΩ cm, to semiconductors, >1000 mΩ cm. Thermal conductivities were low for most compositions, typically 1.5 W m-1 K-1. Nominally undoped Bi2Te2S shows the highest thermoelectric efficiency amongst the tested materials with a ZT = 0.26 at 300 K that decreased to 0.04 at 100 K. The crystal structure of Sb2Te2S, a novel tetradymite-type material, is also reported.
D. C. Grauer et al., "Thermoelectric Properties of the Tetradymite-Type Bi₂Te₂S-Sb₂Te₂S Solid Solution," Materials Research Bulletin, vol. 44, no. 9, pp. 1926-1929, Elsevier, Sep 2009.
The definitive version is available at https://doi.org/10.1016/j.materresbull.2009.05.002
Keywords and Phrases
Carbon Fiber Reinforced Plastics; Chalcogenides; Crystal Structure; Crystallization; Diffraction; Metalloids; Solid Solutions; Solidification; Thermal Conductivity; Thermoanalysis; Thermoelectric Equipment; Tin; X Ray Diffraction; Electric Properties; Electrical Properties; Semiconductivity
International Standard Serial Number (ISSN)
Article - Journal
© 2009 Elsevier, All rights reserved.
01 Sep 2009