Abstract

There has been continued technological and research interest in Nd 2Fe 14B-based compounds due to their excellent intrinsic magnetic properties [(BH) max*∼64MGOe,Ha∼73kOe]. It is found that Ti and Zr substitution in Nd 2Fe 14B leaves its magnetic properties largely unaffected. We have carried out neutron diffraction studies on Zr and Ti substituted 2:14:1 compounds. Three specimens of melt spun alloys of compositions (Nd 0.75Pr 0.25) 12Fe 80B 8, (Nd 0.75Pr 0.25) 8.4Fe 79.7Ti 4.7B 7.2 and (Nd 0.75Pr 0.25) 9.2Fe 79.2Ti 2Zr 2.2B 7.4 were studied. Rietveld refinements reveal that the 4f site is equally occupied by Nd and Pr while the 4g site is occupied only by Nd. In the Ti-containing sample, the lattice expands and Ti is found on the j 1, j 2 sites normally occupied by Fe, (4% and 8%, respectively). This accounts for about 30% of the added Ti. In the third sample, the lattice contracts, which could occur only if Zr replaces the larger rare-earth atoms. However, due to the possibility of four different species occupying the 4f site (i.e., Nd, Pr, Ti, and Zr), it is not possible to determine their relative concentrations from neutron diffraction data alone. The balance of Ti and Zr in this sample must be locked in the grain boundaries. Despite peak broadening associated with the fine grain structure, robust refinements were achieved. © 2002 American Institute of Physics.

Department(s)

Physics

Publication Status

Available Access

International Standard Serial Number (ISSN)

0021-8979

Document Type

Article - Journal

Document Version

Final Version

File Type

text

Language(s)

English

Rights

© 2024 American Institute of Physics, All rights reserved.

Publication Date

15 May 2002

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