Two-photon Sequential Absorption Spectroscopy Of The E(0⁺) State Of Iodine Monofluoride
The energy levels of a new state of iodine monofluoride lying 5 eV above the ground state have been measured using the two-photon sequential absorption technique. Eleven vibrational levels of the state were measured. A vibrational and rotational analysis gives the spectroscopic constants as Te = 41291.96 cm-1, ωe = 248.76 cm-1, ωeχe = 0.4951 cm-1 and Be = 0.12920 cm-1. The state has 0+ character, and dissociates to I+ + F- in the diabatic approximation. © 1986.
B. K. Clark and I. M. Littlewood, "Two-photon Sequential Absorption Spectroscopy Of The E(0⁺) State Of Iodine Monofluoride," Chemical Physics, vol. 107, no. 1, pp. 97 - 103, Elsevier, Aug 1986.
The definitive version is available at https://doi.org/10.1016/0301-0104(86)85063-7
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15 Aug 1986