Quantum and Stochastic Aspects of Low-Temperature Trapping and Reaction Dynamics
We discuss theoretical work on motion-limited trapping kinetics at very low temperatures where theories based upon strictly diffusive models break down due to quantum mechanical effects. In addition, we present numerical results which confirm earlier asymptotic predictions regarding the survival probability for one-dimensional chains, and discuss the important role fluctuations and selfaveraging (or the lack thereof) play in the analysis of finite systems.
P. E. Parris, "Quantum and Stochastic Aspects of Low-Temperature Trapping and Reaction Dynamics," Journal of Statistical Physics, vol. 65, no. 5-6, pp. 1161-1172, Kluwer Academic Publishers-Plenum Publishers, Dec 1991.
The definitive version is available at https://doi.org/10.1007/BF01049605
Keywords and Phrases
Coherence; Reactions; Trapping
International Standard Serial Number (ISSN)
Article - Journal
© 1991 Kluwer Academic Publishers-Plenum Publishers, All rights reserved.