There has been considerable interest recently in the low temperature dynamics of condensed phase tunneling phenomena. In this paper we consider the interplay between quasiparticle transport and vibrational relaxation; the former taking place via tunneling in a double well potential, and the latter occurring due to interactions of the tunneling system with a harmonic bath. Taking the system-bath interactions to be linear in the bath coordinates, and explicitly allowing for a vibrationally excited well, we present a unified treatment of the weak and strong coupling regimes and obtain reduced equations of motion for the tunneling particle position operator. Solutions are obtained for several important limiting cases. In particular, we find that at sufficiently low temperatures, the dynamical behavior strongly resembles that of multisite spin jump model.
P. E. Parris and R. J. Silbey, "Low Temperature Tunneling Dynamics in Condensed Media," Journal of Chemical Physics, vol. 83, no. 11, pp. 5619-5626, American Institute of Physics (AIP), Aug 1985.
The definitive version is available at https://doi.org/10.1063/1.449686
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© 1985 American Institute of Physics (AIP), All rights reserved.
01 Aug 1985