Vanadium Doped Nanostructured TiO₂ Dielectrics
Dielectric properties of titanium oxide ceramics are strongly influenced by the microstructural features and concentration of dopants and impurity ions. Electrical conductivity (via insulation resistance) of vanadium doped nanostructured titanium dioxide (TiO2) ceramics was measured as a function of donor concentration and temperature. In order to further clarify the effect of the dopants on the microstructural development and resultant dielectric properties of TiO2, electron paramagnetic resonance (EPR) spectroscopy was employed. Vanadium-doped TiO2 exhibited well-defined hyperfine splitting characteristics of the 51V nuclei indicating that the dopant ions are dispersed within the grains and not preferentially segregated at the grain boundaries.
F. Dogan et al., "Vanadium Doped Nanostructured TiO₂ Dielectrics," Proceedings of the Materials Research Society (MRS) Symposium Fall Meeting (2013, Boston, MA), vol. 1645, Materials Research Society (MRS), Jan 2014.
The definitive version is available at https://doi.org/10.1557/opl.2014.256
Materials Research Society (MRS) Symposium Fall Meeting (2013: Dec. 1-6, Boston, MA)
Materials Science and Engineering
Keywords and Phrases
ceramic; dielectric properties; nanostructure; Ceramic materials; Electron spin resonance spectroscopy; Grain boundaries; Magnetic resonance; Microstructural evolution
International Standard Serial Number (ISSN)
Article - Conference proceedings
© 2014 Materials Research Society (MRS), All rights reserved.
01 Jan 2014