Ceramic-Metal Composite Formation by Reactive Metal Penetration
Ceramic-metal composites can be made to near-net-shape by reactive penetration of dense ceramic preforms by molten metals. Reactive metal penetration is driven by a strongly negative Gibbs energy for reaction. For Al, the general form of the reaction is (x+2) Al + (3/y) MOy → Al2O3 + M3/yAlx, where MOy is an oxide that is wet by molten Al. In low PO2 atmospheres and at temperatures above about 900⁰C, molten Al reduces mullite to produce Al2O3 and Si. The Al/mullite reaction has a ΔGr⁰(927⁰C) of -338 per mole of mullite and, for fully dense mullite, the theoretical volume change on reaction is less than 1%. Experiments with commercial mullite containing a silicate grain boundary phase average less than 2% volume change on reaction. In the Al/mullite system, reactive metal penetration produces a fine-grained alumina skeleton with an interspersed metal phase. With ≥15 vol.% excess aluminum, mutually interpenetrating ceramic-metal composites are produced. Properties measurements show that ceramic-metal composites produced by reactive metal penetration of mullite by Al have a Young's modulus and hardness similar to that of Al2O3, with improved fracture toughness ranging from 4.5 to 10.5 MPa·m1/2. Other compositions also are candidates for in-situ reaction synthesis, but they exhibit differences in reaction kinetics, most probably due to different wetting behavior. For example, Mg reacts with mullite to form multi-phase composites. These reactions occur at lower temperatures (675⁰-750⁰C) than those for Al/mullite (1100⁰-1500⁰C). In addition, Mg wets mullite more readily than does Al, and Mg more readily subiltrates porous ceramic preforms. The absence of a passivating oxide layer on Mg can account for this behavior.
R. E. Loehman et al., "Ceramic-Metal Composite Formation by Reactive Metal Penetration," Key Engineering Materials, vol. 127-131, pp. 431 - 438, Trans Tech Publications, Jan 1997.
The definitive version is available at https://doi.org/10.4028/www.scientific.net/KEM.127-131.431
Materials Science and Engineering
Keywords and Phrases
Alumina; Ceramic-Metal Composites; In-Situ Reaction; Mullite; Aluminum; Composite materials; Fabrication; Reaction kinetics; Resuborcement; Technology; Reactive metal penetration
International Standard Serial Number (ISSN)
Article - Journal
© 1997 Trans Tech Publications, All rights reserved.
01 Jan 1997