"The rates of oxidation of four chelating agents, NTA, EDTA CDTA, and DTPA with Ce(IV), in sulfuric acid media, were determined spectrophotometrically by a stopped-flow technique. The reductive ability is in the order CDTA>EDTA>DTPA>NTA. The influence of varying the acidity of the medium was studied, and in each case a maximum in the rate constant [H +] plot was observed. A possible interpretation of the reactivities and the influence of acidity is advanced"--Summary, page 1.
Hanna, Samir B.
Webb, William H.
Johnson, James W., 1930-2002
M.S. in Chemistry
University of Missouri--Rolla. Graduate Center for Materials Research
University of Missouri--Rolla
Journal article titles appearing in thesis/dissertation
- The Oxidative Decarboxylation of Polyaminocarboxylic Acids
- A kinetic study of the complex formation and oxidation of diethylenetriaminepentaacetic acid (DTPA) with cerium(IV) in sulfuric acid media
- The oxidative decarboxylation of polyaminocarboxylic acids-III. A study of the reaction of diethylenetriaminepentaacetic acid (DTPA) with cerium (IV) in sulfuric acid media
vii, 46, 20 appendix pages
© 1971 Rita Kathleen Hessley, All rights reserved.
Thesis - Open Access
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Hessley, Rita Kathleen, "The oxidative decarboxylation of aminopolycarboxylic acids with cerium (IV) in sulfuric acid" (1971). Masters Theses. 5491.