Doctoral Dissertations

Abstract

“A detailed paragenetic study of Pb-Zn-Cu ores from the Viburnum Number 28, Brushy Creek, and Goose Creek mines in the Southeast Missouri lead district indicates a complicated paragenesis characterized by repeated periods of mineral deposition. The sequence is composed of nineteen minerals including abundant galena, sphalerite, chalcopyrite, pyrite, marcasite, dolomite, calcite, and quartz and minor siegenite, bornite, bravoite, blaubleibender covellite, covellite, gersdorffite, digenite, enargite, tennantite, dickite, and malachite.

The paragenesis indicates that the ore solutions evolved in the following order: (1) Cu-rich, (2) Co-Ni-rich, (3) Pb-Zn-rich, and (4) Fe-rich. Subsequent repeated generations include cubic galena, later sphalerite, and minor crystalline chalcopyrite and other minerals which occur late in the sequence. Blaubeibender covellite is closely associated with late quartz indicating the introduction of possible supergene solutions at the end stages of mineral deposition.

The general paragenetic sequence corresponds with mineral zoning and is similar throughout the entire lead district. Most importantly, the paragenetically early Cu-Co-Ni sulfides may represent a regional early development of the Cu-Co-Ni-rich mineralization similar to that in the Mine LaMotte-Fredericktown subdistrict and the southern extension of the Viburnum Trend.

It is proposed that a source of Cu, Co, Ni, and some siderophile trace elements may be a series of ultramafic and mafic intrusives controlled by a fracture zone which extends north-northwest from the New Madrid rift towards Fredericktown, Missouri. This fracture zone may represent a transform fault, an epicenter trend, and a distinct, first-order lineament” --Abstract, pages xxiv-xxv.

Advisor(s)

Hagni, Richard D.

Committee Member(s)

Kisvarsanyi, Geza
Proctor, Paul Dean, 1918-1999
Grant, S. Kerry
Mankin, Charles

Department(s)

Geosciences and Geological and Petroleum Engineering

Degree Name

Ph. D. in Geology and Geophysics

Comments

Twelve plates, folded in the back pocket of the manuscript (volume 3), are provided here as supplemental files. Due to their large size, these files may take more time to download.

Each of the 3 volumes attached in the supplemental files can be downloaded separately.

Publisher

University of Missouri--Rolla

Publication Date

Fall 1982

Pagination

3 volumes (xxvii, 652 pages), plates

Note about bibliography

Includes bibliographical references (pages 632-648).

Geographic Coverage

Southeast Missouri

Rights

© 1982 Kenneth Bruce Horrall, All rights reserved.

Document Type

Dissertation - Open Access

File Type

text

Language

English

Thesis Number

T 4841

Print OCLC #

10423688

Horrall_Kenneth_1982_v1.pdf (14053 kB)
Horrall_Kenneth_1982_v2.pdf (18527 kB)
Horrall_Kenneth_1982_v3.pdf (11769 kB)
Horrall_Kenneth_1982_plate1.tif (440819 kB)
I. Generalized Lithofacies Map of the Davis Formation in Missouri

Horrall_Kenneth_1982_plate2.tif (437904 kB)
II. Seismotectonic Map of the Northern Mississippi Embayment Area

Horrall_Kenneth_1982_plate3a.tif (153762 kB)
IIIa. Paragenesis of the Lead-Zinc-Copper Ore from the Viburnum Number 28 Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate3b.tif (61576 kB)
IIIb. Time 1--Partially Correlatable, Detailed Paragenesis of the Early, Large Sphalerite and Earliest, Large Cuboctahedral Galena Generations from the Viburnum Number 28 Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate3c.tif (61747 kB)
IIIc. Time 2--Partially Correlatable, Detailed Paragenesis of the Large Colloform Pyrite Sequence and Interdispersed Cuboctahedral Galena and Bravoite Generations from the Viburnum Number 28 Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate3d.tif (65342 kB)
IIId. Time 2--Partially Correlatable, Detailed Paragenesis of the Large Colloform Pyrite-Marcasite Sequence and Interdispersed Cuboctahedral Galena and Colloform Sphalerite Generations from the Viburnum Number 28 Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate4a.tif (169362 kB)
IVa. Paragenesis of the Lead-Zinc-Copper Ore from the Brushy Creek Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate4b.tif (61547 kB)
IVb. Time 1--Partially Correlatable, Detailed Paragenesis of the Bornite-Chalcopyrite Pod Ore from the Brushy Creek Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate4c.tif (71535 kB)
IVc. Time 2--Partially Correlatable, Detailed Paragenesis of the Earliest Sphalerite from the Brushy Creek Mine, Viburnum Trend Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate5a.tif (177891 kB)
Va. Paragenesis of the Lead-Zinc-Copper Ore from the Goose Creek Mine, Indian Creek Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate5b.tif (63350 kB)
Vb. Time 1--Partially Correlatable, Detailed Paragenesis of the Earliest Sphalerite from the Goose Creek Mine, Indian Creek Subdistrict, Southeast Missouri

Horrall_Kenneth_1982_plate5c.tif (61658 kB)
Vc. Time 2--Partially Correlatable, Detailed Paragenesis of the Large Colloform Pyrite-Marcasite Sequence from the Goose Creek Mine, Indian Creek Subdistrict, Southeast Missouri

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