Theoretical and experimental studies of Sb₄O₆, rhombohedral P₄O₁₀, and crystalline cubic As₄O₆: vibrational analysis, infrared, and Raman spectra

Author

Sean James Gilliam

Keywords and Phrases

Antimony trioxide; Arsenic trioxide; Tetraphosphorous decaoxide

Abstract

"The work described in this dissertation involves the experimental and computational analysis of three 'molecular' group V crystals: Sb₄O₆, P₄O₁₀, and As₄O₆. The overall goal of study was to continue the improvement in theoretical prediction of physical properties of molecules. To accomplish this, this study examined the three group V adamantanoid caged oxides in the infrared (IR) and Raman then compared and contrasted them to theoretical predicted frequencies"--Motivation and Objective, page 1.

Advisor(s)

Kapila, Shubhender
Merrow, Clifton

Committee Member(s)

Ma, Yinfa
Whitefield, Philip D.
Brow, Richard K.

Department(s)

Chemistry

Degree Name

Ph. D. in Analytical Chemistry

Sponsor(s)

United States. Department of the Army

Publisher

University of Missouri--Rolla

Publication Date

Fall 2006

Journal article titles appearing in thesis/dissertation

• Theoretical and experimental study of Sb₄O₆: vibrational analysis, infrared, and Raman spectra
• Theoretical and experimental study of P₄O₁₀: vibrational analysis, infrared and Raman spectra
• Raman spectroscopy of rhombohedral P₄O₁₀
• Theoretical study of As₄O₆: vibrational analysis, infrared, and Raman spectra
• Raman spectroscopy of arsenolite: crystalline cubic As₄O₆

Pagination

xii, 102 pages

Note about bibliography

Includes bibliographical references.

Rights

© 2006 Sean James Gilliam, All rights reserved.

Document Type

Dissertation - Citation

File Type

text

Language

English

Subject Headings

Antimony compounds -- Analysis
Arsenic compounds -- Analysis
Infrared spectra
Molecular structure -- Mathematical models
Phosphorus compounds -- Analysis
Raman effect
Vibrational spectra

Thesis Number

T 9068

Print OCLC #

123423827

Link to Catalog Record

Full-text not available: Request this publication directly from Missouri S&T Library or contact your local library.

Recommended Citation

Gilliam, Sean James, "Theoretical and experimental studies of Sb₄O₆, rhombohedral P₄O₁₀, and crystalline cubic As₄O₆: vibrational analysis, infrared, and Raman spectra" (2006). Doctoral Dissertations. 1694.
https://scholarsmine.mst.edu/doctoral_dissertations/1694