Goldanskii-Karyagin Asymmetry in Fe₃(CO)₁₂

Author

Fernande Grandjean, Missouri University of Science and TechnologyFollow
Gary J. Long, Missouri University of Science and TechnologyFollow
Christopher G. Benson
Umberto Russo

Abstract

The Mössbauer effect spectra of Fe₃(CO)₁₂ have been measured from 4.2 to 295 K and reveal an unusual temperature dependence in the relative area of the two components of the quadrupole doublet associated with the two equivalent iron sites and in the relative area of the two observed quadrupole doublets. The asymmetry in the outer quadrupole doublet is attributed to the Goldanskii-Karyagin effect. The strong temperature dependence of the relative areas of the two quadrupole doublets results from a differing temperature dependence of the recoil free fractions for the two chemically different sites.

Recommended Citation

F. Grandjean et al., "Goldanskii-Karyagin Asymmetry in Fe₃(CO)₁₂," Hyperfine Interactions, vol. 40, no. 2016-01-04, pp. 299 - 302, Springer Verlag, Feb 1988.

The definitive version is available at https://doi.org/10.1007/BF02049102

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0304-3843

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1988 Springer Verlag, All rights reserved.

Publication Date

01 Feb 1988