A Study of the Pressure Induced Irrevesible Conversion of Distorted Tetrahedrahedral Dichloro-trans-2-(2'-quinolyl)methylene-3-quinuclidinonenickel(II), [Ni(qnqn)Cl₂], into Binuclear Square Pyramidal [Ni(qnqn)Cl₂]₂
Abstract
Low-frequency i.r. spectral evidence has been obtained which indicates that the violet distorted tetrahedral complex, Ni(qnqn)Cl2, is irreversibly converted under pressure into its yellow, binuclear, square pyramidal isomer, [Ni(qnqn)Cl2]2; we believe this to be the first irreversible pressure induced solid state structural transformation reported for a transition-metal complex.
Recommended Citation
G. J. Long and J. R. Ferraro, "A Study of the Pressure Induced Irrevesible Conversion of Distorted Tetrahedrahedral Dichloro-trans-2-(2'-quinolyl)methylene-3-quinuclidinonenickel(II), [Ni(qnqn)Cl₂], into Binuclear Square Pyramidal [Ni(qnqn)Cl₂]₂," Journal of the Chemical Society, Chemical Communications, no. 19, pp. 719 - 720, Royal Society of Chemistry, Jan 1973.
The definitive version is available at https://doi.org/10.1039/C39730000719
Department(s)
Chemistry
International Standard Serial Number (ISSN)
0022-4936
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1973 Royal Society of Chemistry, All rights reserved.
Publication Date
01 Jan 1973
