On the Nature of the Spin States in Some Binuclear Iron (III) Complexes
Detailed magnetic, Mössbauer, and spectroscopic studies have been made on a number of binuclear Fe(III) complexes in an effort to determine the spin state for the Fe(III) ions. The over-all data are most consistent with a spin of 5/2 for each iron. An explanation is offered for the presence of a relatively intense electronic absorption band in most of the complexes.
W. M. Reiff et al., "On the Nature of the Spin States in Some Binuclear Iron (III) Complexes," Journal of the American Chemical Society, vol. 90, no. 23, pp. 6347-6351, American Chemical Society (ACS), Nov 1968.
The definitive version is available at https://doi.org/10.1021/ja01025a018
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© 1968 American Chemical Society (ACS), All rights reserved.
01 Nov 1968