The Thermodynamics of Solvation of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System
The solubilities of methane, propane, and n-hexane in the water-sulfuric acid system measured at 283-343 K were used to calculate the thermodynamic functions of solvation at 298 K. An unusual compensation dependence between ΔW°s and ΔS°s, represented by two separate lines corresponding to low and high H2SO4 concentrations, was observed.
A. I. Lutsyk et al., "The Thermodynamics of Solvation of Methane, Propane, and N-Hexane in the Water-Sulfuric Acid System," Russian Journal of Physical Chemistry A, Focus on Chemistry, vol. 73, no. 3, pp. 386-389, Maik Nauka-Interperiodica Publishing, Jan 1999.
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