Concerning the Electron Density at the Pb Nucleus in PbO as a Function of Bond Length

Author

Michal M. Serafin
Sean A. Peebles
Christopher T. Dewberry
Kerry C. Etchinson
Garry S. Grubbs, Missouri University of Science and TechnologyFollow
Robert A. Powoski
Stephen A. Cooke

Abstract

High resolution measurements on the J=1←0 transitions of PbO have been performed using a Fourier transform microwave spectrometer. the available transition frequency for the ²⁰⁸Pb¹⁸O isotopomer has allowed the rotational molecular field shift parameter for lead, V^Pb₀₁, in PbO to be determined for the first time. the parameter gives unique insight concerning how the electron density at the Pb nucleus alters as a function of the Pb-O internuclear separation.

Recommended Citation

M. M. Serafin et al., "Concerning the Electron Density at the Pb Nucleus in PbO as a Function of Bond Length," Chemical Physics Letters, vol. 449, no. 1-2, pp. 33 - 37, Elsevier, Jan 2007.

The definitive version is available at https://doi.org/10.1016/j.cplett.2007.10.031

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0009-2614

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2007 Elsevier, All rights reserved.

Publication Date

01 Jan 2007