Synthesis and X-ray Crystal Structures of Two 14-vertex Di-iron Tetracarbon Metallocarbaboranes
The reaction of Me4C4B8H8 with NaC10H8, NaC5H5, and FeCl 2 produces at least four isomers of [(η5-C 5H5)2Fe2Me4 C 4B8H8], two of which have been structurally characterized from X-ray crystallographic studies and form 14-vertex polyhedra; neither compound has the closo-structure predicted from electron-counting rules, containing instead a 5-membered and a 4-membered open face respectively.
W. M. Maxwell et al., "Synthesis and X-ray Crystal Structures of Two 14-vertex Di-iron Tetracarbon Metallocarbaboranes," Journal of the Chemical Society, Chemical Communications, Royal Society of Chemistry, Jan 1976.
The definitive version is available at https://doi.org/10.1039/C39760000389
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© 1976 Royal Society of Chemistry, All rights reserved.