Magnetic Ordering in [Co(γ-Ch₃C₅H₄NO)₆](ClO₄)₂ I
Crystal structure and superexchange pathways
The crystal structure of the title compound is reported, where the ligand is γ-methylpyridine N-oxide. The crystal data are: space group P21/c, Z = 2, a = 9.498(2) A ̊, b = 10.761(3) A ̊, c = 20.523(7) A ̊, and β = 92.46(2)°. The structure consists of octahedrally-coordinated [Co(γ-CH3C5H4NO)6]2+ ions in a largely two-dimensional network, together with perchlorate ions which exhibit two-fold positional disorder. Likely superexchange paths are discussed. © 1981.
E. Sinn et al., "Magnetic Ordering in [Co(γ-Ch₃C₅H₄NO)₆](ClO₄)₂ I," Physica B+C, Elsevier, Jan 1981.
The definitive version is available at https://doi.org/10.1016/0378-4363(81)90091-7
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© 1981 Elsevier, All rights reserved.