Crystal and Molecular Structure of N-(2-morpholinoethyl)-2-oximato-1-phenylpropan-1-iminechloropalladium(II)
The crystal structure of N-(2-morpholinoethyl)-2-oximato-1-phenylpropan-1-iminechloropalladium(II), [Pd(L)Cl], has been determined from X-ray data collected by counter methods. The compound crystallizes in the orthorhombic space group Pna21 with four molecules per unit cell, the dimensions of which are a=9.602(2), b=8.150(1), c=21.181(4) Å. Full matrix least-squares refinement gave a final R value of 0.042 for the 3218 independent observed reflections. The oxime ligand is deprotonated and is acting as a tridentate ligand coordinating to the palladium through the oxime nitrogen, the imine nitrogen, and the tertiary amine nitrogen of the morpholine moiety. To complete four-coordination about the palladium atom, a chloride ion is also attached to the central metal atom. The donor atoms plus the palladium atom are planar. © 1986 Plenum Publishing Corporation.
K. A. Akinade et al., "Crystal and Molecular Structure of N-(2-morpholinoethyl)-2-oximato-1-phenylpropan-1-iminechloropalladium(II)," Journal of Crystallographic and Spectroscopic Research, Springer Verlag, Jan 1986.
The definitive version is available at http://dx.doi.org/10.1007/BF01161047
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© 1986 Springer Verlag, All rights reserved.