Temperature Dependence of the Proton Nuclear Magnetic Resonance Spectra of Some Diamagnetic N,N-dialkyldithiocarbamate Complexes of Transition Metals

Author

Raymund M. Golding
Peter Conrad Healy
Peter Newman
Ekkehard Sinn, Missouri University of Science and TechnologyFollow
Allen H. White

Abstract

Unusual structure and temperature dependent behavior of the proton nmr spectrum in a number of diamagnetic N,N-dialkyldithiocarbamate complexes of di- and trivalent transition metal ions, [M(CS 2NR 2) n], n = 2, 3 may be accounted for by a total line-shape analysis in terms of an appropriate and general two-proton exchange model using a density matrix formalism. This has been done in detail for a limited range of basic, well-defined, simple, and representative members of the above series, using the diethyl-, di-n-propyl-, diisopropyl-, diisobutyl-, and dibenzyldithiocarbamates of nickel(II) and cobalt(III). Where possible a tentative physical interpretation of the model is given.

Recommended Citation

R. M. Golding et al., "Temperature Dependence of the Proton Nuclear Magnetic Resonance Spectra of Some Diamagnetic N,N-dialkyldithiocarbamate Complexes of Transition Metals," Inorganic Chemistry, American Chemical Society (ACS), Jan 1972.

The definitive version is available at https://doi.org/10.1021/ic50116a029

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0020-1669

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1972 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jan 1972