Thermochemical Isotope Effects. Chloroform/Chloroform-d and Acetone/acetone-d6 in Selected Solvents

Author

Wayne C. Duer
Gary L. Bertrand, Missouri University of Science and TechnologyFollow

Abstract

Isotope effects on the heats of solution of the isotopic pairs chloroform/chloroform-d and acetone/ acetone-d6 have been measured in a variety of solvents at 25°. While both positive and negative isotope effects have been observed for the heats of solution of these solutes, the transfer of the deuterated compound from cyclohexane (at infinite dilution) to other solvents is in every case more exothermic than the transfer of the parent compound.

Recommended Citation

W. C. Duer and G. L. Bertrand, "Thermochemical Isotope Effects. Chloroform/Chloroform-d and Acetone/acetone-d6 in Selected Solvents," Journal of the American Chemical Society, American Chemical Society (ACS), Jan 1974.

The definitive version is available at https://doi.org/10.1021/ja00812a006

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0002-7863

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1974 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jan 1974