A Scaled Nucleation Model for Ideal Binary Systems
A scaled binary nucleation model for ideal systems is presented and used to analyze the experimental hexanol-ethanol data of Strey and Viisanen at 260 K. A major feature of the scaled nucleation rate is the rate prefactor, J0, which is only weakly T (and composition) dependent and here is approximated by a constant. The model gives surprisingly good agreement with the experimental activity plot, and the scaled model method for finding the critical cluster composition (with binary surface tension composition variation) provides a better fit to the experimental data than the revised classical model.
B. N. Hale and G. Wilemski, "A Scaled Nucleation Model for Ideal Binary Systems," Chemical Physics Letters, vol. 305, no. 3-4, pp. 263-268, Elsevier, May 1999.
The definitive version is available at https://doi.org/10.1016/S0009-2614(99)00365-6
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