"The anodic dissolution of molybdenum in 1.0 N HNO₃ (pH = 0.3) , 0.1 N HNO₃-0.9 N KNO₃ (pH = 1.2), and 0.01 N HNO₃ -0.99 N KNO₃ (pH = 2.1) was investigated. The following conclusions were possible: 1. Mo is in general electrochemically oxidized to the Mo-VI state during anodic dissolution. 2. The resultant ions in solution are HMOO⁻₄. 3. The Mo surface in aqueous solutions is covered with an oxide whose approximate composition is Mo₂O₅. 4. The polarization curves have a linear Tafel region at potentials slightly above the rest potential. 5. There is no significant effect of pH on the anodic dissolution. 6. The anodic dissolution is controlled by the oxidation of the surface oxide (Mo₂O₅) to MoO₃"--Abstract, Page ii.
Johnson, James W., 1930-2002
James, William Joseph
O'Keefe, T. J. (Thomas J.)
Chemical and Biochemical Engineering
M.S. in Chemical Engineering
Missouri University of Science and Technology. Graduate Center for Materials Research
University of Missouri--Rolla
xiv, 68 Pages
© 1970 Kuan-hsiung Hoh, All rights reserved.
Thesis - Open Access
Library of Congress Subject Headings
Metals -- Anodic oxidation
Corrosion and anti-corrosives
Print OCLC #
Electronic OCLC #
Link to Catalog Recordhttp://laurel.lso.missouri.edu/record=b1067179~S5
Hoh, Kuan-hsiung, "The anodic dissolution of molybdenum in acidic nitrate solutions" (1970). Masters Theses. 7036.