Abstract

Municipal solid waste incineration (MSWI) bottom ash (MBA) represents both a disposal challenge and a potential resource for sustainable construction materials, including use as a supplementary cementitious material (SCM). However, the conventional use of MBA in cement-based materials is hindered by its high metallic aluminum content, which reacts in alkaline environments to release hydrogen gas and causes volumetric instability (e.g., expansion and cracking). This study investigates a cement-based alkali pretreatment method using diluted cement suspension to stabilize metallic aluminum and improve the compatibility of MBA as an SCM. Compared to conventional alkali solutions, the proposed approach avoids the direct use of highly concentrated chemical alkalis and may offer practical advantages for integration into cementitious systems. The pretreatment generated approximately 2.4-2.6 kg of hydrogen gas per metric ton of MBA, and the treated MBA achieved substantially improved performance compared to untreated MBA, retaining over 75% of the control compressive strength at later ages with 20% cement substitution. Preliminary lifecycle and economic assessments indicated reduced CO2 emissions and more than 25% potential cost savings compared to conventional Portland cement systems. The results demonstrate that cement-based alkali pretreatment can improve the performance of MBA as an SCM in cementitious systems while supporting effective solid waste valorization.

Department(s)

Civil, Architectural and Environmental Engineering

Publication Status

Full Text Access

Comments

Environmental Research and Education Foundation, Grant 2214028

Keywords and Phrases

Alkali treatment; Hydrogen recovery; Metallic aluminum; Municipal solid waste incineration bottom ash; Solid waste valorization; Supplementary cementitious material

International Standard Serial Number (ISSN)

0958-9465

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2026 Elsevier, All rights reserved.

Publication Date

01 Oct 2026

Share

 
COinS