Abstract

This paper presents the results of a laboratory study on the effect of pH (2, 5, and 9) and gas-phase ozone concentration (1, 7, and 11 wt. %) on the decolorization efficiency via ozonation for seven common textile dyes. Higher gas-phase ozone concentrations resulted in higher decolorization rates due to more rapid ozone transfer. Higher gas-phase ozone concentration, however, was also observed to have a positive, neutral, or negative effect on ozone dose requirements for different dyes. In general, greater ozone utilization efficiency was achieved at lower pH levels where direct ozone reactions predominate. It was observed that because ozonation can cause significant resolubilization of precipitated dyes, complete removal of dye precipitate should be accomplished prior to polishing via ozonation. The results point to the need for laboratory and/or pilot testing for dye-laden waste streams to allow process optimization.

Department(s)

Civil, Architectural and Environmental Engineering

Second Department

Chemistry

Keywords and Phrases

Dyes; Laboratory tests; Ozone; Wastewater

International Standard Serial Number (ISSN)

0733-9372

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2024 American Society of Civil Engineers, All rights reserved.

Publication Date

01 Mar 2002

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