β,β-dichlorovinyldiazonium or Dichloro(diazomethyl)carbenium Ion? Crystal Structure and Electron Density Distribution of β,β- Dichlorovinyldiazonium Hexachloroantimonate

Author

Grace Shiahuy Chen
Rainer Glaser, Missouri University of Science and TechnologyFollow
Charles Leslie Barnes

Abstract

The crystal structure of β,β-dichlorovinyldiazonium hexachloroantimonate, 2·SbCl₆, and the topological electron density analysis of 2 provide compelling evidence for the importance of chlorine-stabilized carbenium ion resonance forms for the stabilization of vinyldiazonium ions by β-substitution.

Recommended Citation

G. S. Chen et al., "β,β-dichlorovinyldiazonium or Dichloro(diazomethyl)carbenium Ion? Crystal Structure and Electron Density Distribution of β,β- Dichlorovinyldiazonium Hexachloroantimonate," Journal of the Chemical Society, Chemical Communications, no. 19, pp. 1530 - 1532, Royal Society of Chemistry, Jan 1993.

The definitive version is available at https://doi.org/10.1039/C39930001530

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0022-4936

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1993 Royal Society of Chemistry, All rights reserved.

Publication Date

01 Jan 1993