Title

An Open-framework Iron Phosphate with Large Voids, Exhibiting Spin-crossover

Abstract

A novel iron phosphate, [(C4N3H16)(C4N3H15)]5+-[Fe5F4(H2PO4)(HPO4)3(PO4)3]5-·H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1999 Royal Society of Chemistry, All rights reserved.


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