Title

Ab Initio/IGLO Study of Strained Bicyclic Olefins

Abstract

The 13C NMR chemical shifts of strained olefins 1, 2, 3, and 6 were calculated using the ab initio/IGLO method(DZ/6-31G*). The calculated values resemble the experimental data closely but show a systematic drift with increased strain. The chemical shifts of the yet unknown olefins 1 and 2 were predicted to be extremely deshielded.

Department(s)

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1992 American Chemical Society (ACS), All rights reserved.


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