NMR-Detection of Intermediates During Homogeneous Hydrogenation of Dienes using Parahydrogen
The 1H-NMR spectra of the reaction products of hydrogenations using parahydrogen reveal information about intermediates and thus the reaction mechanism. Due to its high signal enhancement the method is uniquely suited for reactions, where the catalyst itself becomes chemically modified.
J. Bargon et al., "NMR-Detection of Intermediates During Homogeneous Hydrogenation of Dienes using Parahydrogen," Tetrahedron Letters, vol. 31, no. 40, pp. 5721-5724, Elsevier, Apr 1990.
The definitive version is available at http://dx.doi.org/10.1016/S0040-4039(00)97941-3
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