Experimental P-T-P Measurements of Carbon Dioxide and 1, 1-difluoroethane Mixtures
Pressure and temperature data were experimentally measured for binary supercritical mixtures of carbon dioxide and 1,1-difluoroethene. The temperature range for the experiments was from 310 K to 370 K. The pressure range was from 7.0 MPa to 31.0 MPa. It was determined that the Peng-Robinson equation of state can predict fluid behavior of supercritical carbon dioxide and 1,1-difluoroethene with a deviation of 2.5% ± 0.1%. A binary interaction parameter was obtained from a regression analysis over the temperature range of interest.
J. E. Wenzel et al., "Experimental P-T-P Measurements of Carbon Dioxide and 1, 1-difluoroethane Mixtures," Journal of Chemical and Engineering Data, American Chemical Society (ACS), Mar 2005.
The definitive version is available at http://dx.doi.org/10.1021/je0499770 S0021-9568(04)09977-7
Chemical and Biochemical Engineering
Keywords and Phrases
McMillan-Mayer Theory; Enthalpies; Microcalorimetry; Polylols
Article - Journal
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