Abstract
Maraging steels are known for their exceptional strength but suffer from limited work hardening and ductility. Here, we report an intermittent printing strategy to tailor the microstructure and mechanical properties of maraging 250 steel via tuning the thermal history during wire-arc directed energy deposition. By introducing a dwell time between adjacent layers, the maraging 250 steel is cooled below the martensite start temperature, triggering thermally driven martensitic transformation during the printing process. Thermal cycling during subsequent layer deposition results in the formation of reverted austenite which shows a refined microstructure and induces elemental segregation between martensite and reverted austenite. The Ni enrichment in the austenite promotes stabilization of the reverted austenite upon cooling to room temperature. The reverted austenite is metastable during deformation, leading to strain-induced martensitic transformation under loading. Specifically, a 3 min interlayer dwell time produces a maraging 250 steel with approximately 8% reverted austenite, resulting in improved work hardening via martensitic transformation induced plasticity during deformation. Meanwhile, the higher cooling rate and refined prior austenite grains lead to substantially refined martensitic grains (by approximately fivefold) together with an increased dislocation density. With 3 min interlayer dwell time, the yield strength of the printed maraging 250 steel increases from 836 MPa to 990 MPa, and the uniform elongation is doubled from 3.2% to 6.5%. This intermittent deposition strategy demonstrates the potential to tune the microstructure of maraging steels for achieving strength-ductility synergy by engineering the thermal history during additive manufacturing.
Recommended Citation
S. Mooraj and S. Feng and M. Luebbe and M. Register and J. Liu and T. Li and B. Yavas and D. P. Schmidt and M. W. Priddy and M. B. Nicholas and V. K. Champagne and M. Aindow and H. Wen and W. Chen, "Martensitic Transformation Induced Strength-ductility Synergy in Additively Manufactured Maraging 250 Steel by Thermal History Engineering," Journal of Materials Science and Technology, vol. 211, pp. 212 - 225, Elsevier, Mar 2025.
The definitive version is available at https://doi.org/10.1016/j.jmst.2024.05.062
Department(s)
Materials Science and Engineering
Keywords and Phrases
Additive manufacturing; Maraging steel; Martensitic transformation; Mechanical properties; Thermal history
International Standard Serial Number (ISSN)
1005-0302
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2025 Elsevier, All rights reserved.
Publication Date
10 Mar 2025
Comments
U.S. Department of Energy, Grant HQ0034-15-2-0007