Palladium(ii) Complexes Containing 2,6-bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions
A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change δSz.ast;, enthalpy change δH#, and Gibbs free energy change δG# of the thermal decomposition were calculated by means of several methods based on the single heating rate.
O. Dayan et al., "Palladium(ii) Complexes Containing 2,6-bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions," Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, vol. 40, no. 5, pp. 337-344, Taylor and Francis, May 2010.
The definitive version is available at https://doi.org/10.1080/15533174.2010.486822
Materials Science and Engineering
Keywords and Phrases
Activation energy; Pd(II) complexes; Pyridine-2,6-diimines; Suzuki reaction; Thermal behavior
International Standard Serial Number (ISSN)
Article - Journal
© 2010 Taylor and Francis, All rights reserved.
01 May 2010