Mechanisms of base-catalyzed reactions: Part III: The acidities of some hydroxylic compounds in t-butyl alcohol.
"The KHA of water and five alcohols were determined in t̲-butyl alcohol employing sodium and potassium t̲-butoxides. The order of acidity is methanol>water>ethanol> 2-propanol~cyclohexanol>methanol. It was also shown that potassium t̲-butoxide was twice as strong a base as sodium t̲-butoxide. A spectrophotometric method was employed with p-nitroaniline as the indicator. Calculations were made employing the methods of Stearns and Wheland and of Hine and Hine"--Abstract, page iii.
Wulfman, David S., 1934-2013
Hanna, Samir B.
Mayhan, Kenneth G.
Bertrand, Gary L.
M.S. in Chemistry
University of Missouri at Rolla. Department of Chemistry
University of Missouri at Rolla
© 1967 Charles Frederick Seger, All rights reserved.
Thesis - Open Access
Alcohols -- Reactivity
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Seger, Charles Frederick, "Mechanisms of base-catalyzed reactions: Part III: The acidities of some hydroxylic compounds in t-butyl alcohol." (1967). Masters Theses. 5039.