Potential to Design Magnesium Potassium Phosphate Cement Paste Based on an Optimal Magnesia-to-Phosphate Ratio
Magnesium potassium phosphate cement (MKPC) is an important engineering material, and it has been attracting increasing attention. Properties of MKPC based materials depend largely on the magnesia-to-phosphate molar ratio (M/P) and the water-to-cement mass ratio (W/C). While the effect of W/C has been clear, experimental results of the effect of M/P in the literature seem to be inconsistent. In this paper, a model is developed to unify these experimental findings. The model hypothesizes that the strength of MKPC based materials is dominated by the volume ratio of magnesium potassium phosphate hexahydrate and space (MKP/space ratio), and the ultimate MKP/space ratio can be limited by the availabilities of the three reactants, i.e. magnesia, phosphate and water. It proves that, if the W/C of MKPC-based material is kept constant, there exists an optimal M/P that results in the highest compressive strength. It appears that the higher the W/C is, the smaller this optimal M/P will be.
H. Ma and B. Xu, "Potential to Design Magnesium Potassium Phosphate Cement Paste Based on an Optimal Magnesia-to-Phosphate Ratio," Materials and Design, vol. 118, pp. 81-88, Elsevier Ltd, Mar 2017.
The definitive version is available at https://doi.org/10.1016/j.matdes.2017.01.012
Civil, Architectural and Environmental Engineering
Keywords and Phrases
Cements; Compressive Strength; Magnesia; Magnesium; Microstructure; Phosphates; Potassium; Chemically Bonded Ceramics; Engineering Materials; Magnesium Potassium Phosphate Cements; Magnesium Potassium Phosphate Hexahydrates; Mass Ratio; MKP/Space Ratio; Molar Ratio; Volume Ratio; Strength of Materials
International Standard Serial Number (ISSN)
Article - Journal
© 2017 Elsevier Ltd, All rights reserved.
01 Mar 2017