Microscopic and Physicochemical Studies of Polymer-Modified Kaolinite Suspensions
Abstract
Sedimentation tests on kaolinite in biopolymers (xanthan gum, chitosan, polyacrylic acid and polyacrylamide) solutions were conducted and recorded with time-lapsed technique up to 35 days. Microscopic particle size, zeta potential, final volume and solid content were measured along the elevation of the graduated cylinder at the end of tests, and settling velocity and intensity calculated. Test results suggested that positive charged edges of kaolinite particles attached to negatively-charged xanthan gum (0.001 and 0.5 g/l) long chain via electrostatic force, exhibiting edge-to-edge (EE) fabric structure, and that charge neutralization was the primary interaction mechanism between kaolinite and either chitosan (0.05 and 5 g/l) or PAA(0.05 and 1 g/l),and that steric stabilization dominates the interaction between kaolinite and PAM molecules at 0.1 and 0.5 g/l PAM solutions.
Recommended Citation
J. Cao et al., "Microscopic and Physicochemical Studies of Polymer-Modified Kaolinite Suspensions," Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 554, pp. 16 - 26, Elsevier, Oct 2018.
The definitive version is available at https://doi.org/10.1016/j.colsurfa.2018.06.019
Department(s)
Civil, Architectural and Environmental Engineering
Keywords and Phrases
Biopolymers; Microscopic particle size; Time-lapse; Zeta potential
International Standard Serial Number (ISSN)
1873-4359; 0927-7757
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2024 Elsevier, All rights reserved.
Publication Date
05 Oct 2018
Comments
National Natural Science Foundation of China, Grant 51779219