Performance of Pilot-Scale Constructed Wetlands for Secondary Treatment of Chromium-Bearing Tannery Wastewaters

Abstract

Tannery operations consist of converting raw animal skins into leather through a series of complex water- and chemically-intensive batch processes. Even when conventional primary treatment is supplemented with chemicals, the wastewater requires some form of biological treatment to enable the safe disposal to the natural environment. Thus, there is a need for the adoption of low cost, reliable, and easy-to-operate alternative secondary treatment processes. This paper reports the findings of two pilot-scale wetlands for the secondary treatment of primary effluents from a full tannery operation in terms of resilience (i.e., ability to produce consistent effluent quality in spite of variable influent loads) and reliability (i.e., ability to cope with sporadic shock loads) when treating this hazardous effluent. Areal mass removal rates of 77.1g COD/m2/d, 11g TSS/m2/d, and 53mg Cr/m2/d were achieved with a simple gravity-flow horizontal subsurface flow unit operating at hydraulic loading rates of as much as 10cm/d. Based on the findings, a full-scale wetland was sized to treat all the effluent from the tannery requiring 68% more land than would have been assumed based on literature values. Constructed wetlands can offer treatment plant resilience for minimum operational input and reliable effluent quality when biologically treating primary effluents from tannery operations.

Department(s)

Civil, Architectural and Environmental Engineering

Keywords and Phrases

Anaerobic; Animal skins; Areal mass; Batch process; Biological treatment; Constructed wetlands; Effluent quality; Horizontal flow constructed wetlands; Horizontal subsurface flow; Hydraulic loading rates; Influent loads; Low costs; Natural environments; Pilot scale; Primary effluent; Primary treatment; Safe disposals; Secondary treatment; Shock load; Sizing; Tannery wastewater; Treatment plants; Batch data processing; Chromium; Effluent treatment; Effluents; Gravitation; Solids; Wastewater disposal; Water quality; Wetlands; Chemicals removal (water treatment); Chromium; Industrial effluent; Anoxic conditions; Chemical industry; Performance Assessment; Skin; Waste treatment; Wastewater; Argentina; Article; Biochemical oxygen demand; Chemical composition; Chemical oxygen demand; Ecosystem resilience; Gravity; Leather industry; Reliability; Sewage effluent; Suspended particulate matter; Waste water management; Adsorption; Industrial Waste; Pilot Projects; Tanning; Waste Disposal; Fluid; Water Pollutants; Chemical; Wetlands; Animalia; Sizing

International Standard Serial Number (ISSN)

0304-3894

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2012 Elsevier, All rights reserved.

Publication Date

01 Nov 2012

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