Solid State Dynamics of Fe₃(CO)₁₂ Revisited
An analysis of the temperature dependence of the Mössbauer spectral hyperfine parameters of Fe3(CO)12, in conjunction with recently reported temperature-dependent X-ray structural results, indicates different temperature dependences for the recoil-free fractions of the two iron sites, completely supports the presence of Goldanskii-Karyagin asymmetry in the Mössbauer spectra of this compound, and eliminates the possibility of 60° rotational disorder for the iron sites, at least on the Mössbauer time scale.
F. Grandjean and G. J. Long, "Solid State Dynamics of Fe₃(CO)₁₂ Revisited," Inorganic Chemistry, vol. 35, no. 16, pp. 4532-4533, American Chemical Society (ACS), Jul 1996.
The definitive version is available at https://doi.org/10.1021/ic960248i
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© 1996 American Chemical Society (ACS), All rights reserved.
01 Jul 1996