Solid State Dynamics of Fe₃(CO)₁₂ Revisited

Author

Fernande Grandjean, Missouri University of Science and TechnologyFollow
Gary J. Long, Missouri University of Science and TechnologyFollow

Abstract

An analysis of the temperature dependence of the Mössbauer spectral hyperfine parameters of Fe₃(CO)₁₂, in conjunction with recently reported temperature-dependent X-ray structural results, indicates different temperature dependences for the recoil-free fractions of the two iron sites, completely supports the presence of Goldanskii-Karyagin asymmetry in the Mössbauer spectra of this compound, and eliminates the possibility of 60° rotational disorder for the iron sites, at least on the Mössbauer time scale.

Recommended Citation

F. Grandjean and G. J. Long, "Solid State Dynamics of Fe₃(CO)₁₂ Revisited," Inorganic Chemistry, vol. 35, no. 16, pp. 4532 - 4533, American Chemical Society (ACS), Jul 1996.

The definitive version is available at https://doi.org/10.1021/ic960248i

Department(s)

Chemistry

International Standard Serial Number (ISSN)

0020-1669

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1996 American Chemical Society (ACS), All rights reserved.

Publication Date

01 Jul 1996