A New Type of Polycyclophosphidochromium Cluster, [(Cp)Cr(CO)₂]₅P₁₀ (Cp = Η⁵-C₅H₅)
First observation of polycylic P-to-M coordination
The co-thermolysis of [(Cp)Cr(CO)3]2 (Cp = η5-C5H5) with P4 forms [(Cp)Cr(CO)2]5P10, a new paramagnetic structure with a P10 core, which represents the first example of polycyclic phosphorus-to-metal coordination.
L. Y. Goh et al., "A New Type of Polycyclophosphidochromium Cluster, [(Cp)Cr(CO)₂]₅P₁₀ (Cp = Η⁵-C₅H₅)," Journal of the Chemical Society, Chemical Communications, Royal Society of Chemistry, Jan 1990.
The definitive version is available at https://doi.org/10.1039/C39900001484
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© 1990 Royal Society of Chemistry, All rights reserved.