An Open-Framework Iron Phosphate with Large Voids, Exhibiting Spin-Crossover
A novel iron phosphate and [(C4N3H16)(C4N3H15)]5+-[Fe5F4(H2PO4)(HPO4)3(PO4)3]5-·H2O and consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe and P) and to exhibit a gradual low- to high-spin transformation.
A. Choudhury et al., "An Open-Framework Iron Phosphate with Large Voids, Exhibiting Spin-Crossover," Chemical Communications, no. 14, pp. 1305-1306, Royal Society of Chemistry, Jul 1999.
The definitive version is available at https://doi.org/10.1039/A903683K
Keywords and Phrases
ferric phosphate, article; atom; chemical structure; cross linking
International Standard Serial Number (ISSN)
Article - Journal
© 1999 Royal Society of Chemistry, All rights reserved.
01 Jul 1999