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Title: Personal reactive clouds: Introducing the concept of near-head chemistry
Author (s): Corsi, R.L.
Siegel, J.
Karamalegos, A.
Simon, H.
Morrison, Glenn
Department/Lab Affiliations: Civil, Architectural & Environmental Engineering
Environmental Research Center
Keywords: Breathing zone.
Reaction products.
Ultra fine particles.
Subject Terms: Ozone
Terpenes.
Issue Date: 2007
Publisher: Elsevier
Citation: Corsi, R.L., Siegel, J., Karamalegos, A., Simon, H., and Morrison, G.C. Personal reactive clouds: introducing the concept of near head chemistry. Atmospheric Environment. 2007 41(15): 3161-3165.
Abstract: The “personal cloud” effect and its impact on human exposure to airborne pollutants are well documented. A great deal is also known regarding indoor air chemistry, particularly as related to ozone reactions with mono-terpenes. In this paper we hypothesize the presence of personal reactive clouds that result from ozone reactions with terpenes and terpenoids emitted from personal care products. A proof of concept assessment was completed based on reaction rates between ozone and five reactive organic compounds that are found in personal care products. Screening experiments were also completed with three perfumes and two hairsprays to determine the extent of secondary organic aerosol formation in the breathing zone of a subject who had applied these products. The results of screening calculations and preliminary experiments confirm that chemistry occurs in the near-head region of individuals who apply scented personal care products to their hair or facial skin. Additional research is needed to characterize reaction products and health consequences associated with near-head chemistry and associated personal reactive clouds.
Type: Article - Journal
text
Copyright Notice: This material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder.
FULL COPYRIGHT INFORMATION:
http://www.elsevier.com/wps/find/authorsview.authors/authorsrights
Publisher URL:
http://dx.doi.org/10.1016/j.atmosenv.2006.07.054
Link to this page:
http://scholarsmine.mst.edu/post_prints/PersonalReactiveClouds_09007dcc80431224.html



titlePersonal reactive clouds: Introducing the concept of near-head chemistry
contributor.authorCorsi, R.L.
contributor.authorSiegel, J.
contributor.authorKaramalegos, A.
contributor.authorSimon, H.
contributor.authorMorrison, Glenn
contributor.deptlabCivil, Architectural & Environmental Engineering
contributor.deptlabEnvironmental Research Center
contributor.sponsorNational Science Foundation
subjectBreathing zone.
subjectReaction products.
subjectUltra fine particles.
subject.LCSHOzone
subject.LCSHTerpenes.
date.issued2007
publisherElsevier
identifier.citationCorsi, R.L., Siegel, J., Karamalegos, A., Simon, H., and Morrison, G.C. Personal reactive clouds: introducing the concept of near head chemistry. Atmospheric Environment. 2007 41(15): 3161-3165.
identifier.pub.URI
http://dx.doi.org/10.1016/j.atmosenv.2006.07.054
description.abstractThe “personal cloud” effect and its impact on human exposure to airborne pollutants are well documented. A great deal is also known regarding indoor air chemistry, particularly as related to ozone reactions with mono-terpenes. In this paper we hypothesize the presence of personal reactive clouds that result from ozone reactions with terpenes and terpenoids emitted from personal care products. A proof of concept assessment was completed based on reaction rates between ozone and five reactive organic compounds that are found in personal care products. Screening experiments were also completed with three perfumes and two hairsprays to determine the extent of secondary organic aerosol formation in the breathing zone of a subject who had applied these products. The results of screening calculations and preliminary experiments confirm that chemistry occurs in the near-head region of individuals who apply scented personal care products to their hair or facial skin. Additional research is needed to characterize reaction products and health consequences associated with near-head chemistry and associated personal reactive clouds.
typeArticle - Journal
type.DCMITypetext
type.statusFinal version
rightsThis material is presented to ensure timely dissemination of scholarly and technical work. Copyright and all rights therein are retained by authors or by other copyright holders. All persons copying this information are expected to adhere to the terms and constraints invoked by each author's copyright. In most cases, these works may not be reposted without the explicit permission of the copyright holder.
rights.URI
http://www.elsevier.com/wps/find/authorsview.authors/authorsrights
date.accessioned2007-04-11T17:00:48Z
date.available2007-12-17T20:53:19Z
identifier.persist.URI
http://scholarsmine.mst.edu/post_prints/PersonalReactiveClouds_09007dcc80431224.html