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Title: Dual-layer dye-filled developer-soluble BARCs for 193-nm lithography
Author (s): Meador, Jim D.
Beaman, Carol
Stroud, Charlyn
Lowes, Joyce A.
Drain, David
Department/Lab Affiliations: Design Engineering Center
Mathematics & Statistics
Keywords: 193-nm microlithography
BARC
Guerrero, Douglas J.
Mercado, Ramil-Marcelo L.
Zhu, Zhimin
anti-reflective
developer-soluble
dual-layer
immersion
Issue Date: 2008-03
Publisher: Society of Photo-Optical Instrumentation Engineers SPIE
Citation: Jim D. Meador, Carol Beaman, Charlyn Stroud, Joyce A. Lowes, Zhimin Zhu, Douglas J. Guerrero, and Ramil-Marcelo L. Mercado(2008). Dual-layer dye-filled developer-soluable BARCs for 193-nm litholgraphy. Proceedings of SPIE, Vol. 6923, 69232W
Abstract: A family of dye-filled developer-soluble bottom anti-reflective coatings (BARCs) has been developed for use in 193-nm microlithography. This new dye-filled chemical platform easily provides products covering a wide range of optical properties. The light-sensitive and positive-working BARCs use a transparent polymeric binder and a polymeric dye in a thermally crosslinking formulation, with the cured products then being photochemically decrosslinked prior to development. The cured BARC films are imaged and removed with developer in the same steps as the covering photoresist. Two dye-filled BARCs with differing optical properties were developed via a series of DOEs and then used as a dual-layer BARC stack. Lithography with this BARC stack, using a 193-nm resist, gave 150-nm L/S (1:1). A 193-nm dual-layer BARC stack (gradient optical properties) from the well-established dye-attached family of light-sensitive BARCs also gave 150-nm L/S (1:1) with the same resist. However, the latter provided much improved line shape with no scumming. The targeted application for light-sensitive dual-layer BARCs is high-numerical aperture (NA) immersion lithography where a single-layer BARC will not afford the requisite reflection control.
Type: Article - Conference proceedings
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Publisher URL:
http://dx.doi.org/10.1117/12.772793
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titleDual-layer dye-filled developer-soluble BARCs for 193-nm lithography
contributor.authorMeador, Jim D.
contributor.authorBeaman, Carol
contributor.authorStroud, Charlyn
contributor.authorLowes, Joyce A.
contributor.authorDrain, David
contributor.deptlabDesign Engineering Center
contributor.deptlabMathematics & Statistics
subject193-nm microlithography
subjectBARC
subjectGuerrero, Douglas J.
subjectMercado, Ramil-Marcelo L.
subjectZhu, Zhimin
subjectanti-reflective
subjectdeveloper-soluble
subjectdual-layer
subjectimmersion
date.issued2008-03
publisherSociety of Photo-Optical Instrumentation Engineers SPIE
identifier.citationJim D. Meador, Carol Beaman, Charlyn Stroud, Joyce A. Lowes, Zhimin Zhu, Douglas J. Guerrero, and Ramil-Marcelo L. Mercado(2008). Dual-layer dye-filled developer-soluable BARCs for 193-nm litholgraphy. Proceedings of SPIE, Vol. 6923, 69232W
identifier.pub.URI
http://dx.doi.org/10.1117/12.772793
description.abstractA family of dye-filled developer-soluble bottom anti-reflective coatings (BARCs) has been developed for use in 193-nm microlithography. This new dye-filled chemical platform easily provides products covering a wide range of optical properties. The light-sensitive and positive-working BARCs use a transparent polymeric binder and a polymeric dye in a thermally crosslinking formulation, with the cured products then being photochemically decrosslinked prior to development. The cured BARC films are imaged and removed with developer in the same steps as the covering photoresist. Two dye-filled BARCs with differing optical properties were developed via a series of DOEs and then used as a dual-layer BARC stack. Lithography with this BARC stack, using a 193-nm resist, gave 150-nm L/S (1:1). A 193-nm dual-layer BARC stack (gradient optical properties) from the well-established dye-attached family of light-sensitive BARCs also gave 150-nm L/S (1:1) with the same resist. However, the latter provided much improved line shape with no scumming. The targeted application for light-sensitive dual-layer BARCs is high-numerical aperture (NA) immersion lithography where a single-layer BARC will not afford the requisite reflection control.
typeArticle - Conference proceedings
type.DCMITypetext
rightsNo full text allowed
rights.URI
http://spie.org/x1126.xml
date.available2008-09-19T19:09:55Z
identifier.persist.URI
http://scholarsmine.mst.edu/post_prints/Dual-LayerDye-FilledDeveloper-SolubleBARCsFor19_09007dcc80573699.html