Entropy and Enthalpy Change in Hydrated Ion Clusters
A new electrothermodynamic theory was recently developed by (Suck) Salk to treat the hydration of ions suspended in a gas containing water vapor. This theory was successfully applied to a study of the free energy of formation of both positive and negative ions and to an analysis of ion mobility data. Here the new theory is used to study entropy and enthalpy for a variety of hydrated ions. The results compare favorably to experiment and are significantly superior to Thomson theory results.
D. E. Hagen and S. S. Salk, "Entropy and Enthalpy Change in Hydrated Ion Clusters," Chemical Physics, vol. 102, no. 3, pp. 459-466, Elsevier, Mar 1986.
The definitive version is available at http://dx.doi.org/10.1016/0301-0104(86)80016-7
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