Atomic Collision Parameters for Electron De-Excitation of the 4S-3P Transition of Sodium
A comparison of measured Stokes parameters and atomic collision parameters (Plin, γ, L⊥, P+) is made for the excitation and de-excitation of the 3S-3P and 4S-3P transitions of Na respectively, for electrons with incident energies of 22, 30 and 50 eV. These parameters are obtained from 'time-inverse' experiments in which electrons are either superelastically (3P-3S) or inelastically (3P-4S) scattered from the laser prepared 3P state. The data are compared with calculations from a convergent close coupling (CCC) model and a second-order distorted wave Born (DWB2) model. Both models demonstrate very good agreement for 3S-3P transitions. For the 4S-3P transitions, the DWB2 is in better accord with experiment than the CCC for the Plin parameter, the CCC is in excellent agreement with experiment for γ and L⊥, and neither is in accord with experiment for P+.
M. Shurgalin et al., "Atomic Collision Parameters for Electron De-Excitation of the 4S-3P Transition of Sodium," Journal of Physics B: Atomic, Molecular and Optical Physics, vol. 32, no. 10, pp. 2439-2459, IOP, Bristol, United Kingdom, May 1999.
The definitive version is available at https://doi.org/10.1088/0953-4075/32/10/312
Keywords and Phrases
Electron energy levels; Electron scattering; Electron transitions; Electrons; Laser applications; Mathematical models; Molecular dynamics; Atomic collision parameters; Convergent close coupling model; Second order distorted wave born; Stokes parameters; Sodium
International Standard Serial Number (ISSN)
Article - Journal
© 1999 IOP, Bristol, United Kingdom, All rights reserved.