Atomic Structures of Two Rhombohedral Ferroelectric Phases in the Pb(Zr, Ti)O₃ Solid Solution Series

Author

Christian Michel
Jean-Michel Moreau
Gary D. Achenbach
Robert Gerson, Missouri University of Science and TechnologyFollow
William Joseph James, Missouri University of Science and TechnologyFollow

Abstract

The atomic positions in perovskitic PbZrxTi1-xO3 were determined for x = 0.9 and x = 0.58, using X-ray and neutron diffraction. The space group is R3c for x = 0.9, the unit cell containing two formula units of the compound, and R3m for x = 0.58, the unit cell containing one formula unit. A linear relationship is found between the displacements of the two cations in isomorphous ferroelectric of the R3c space group. © 1969.

Recommended Citation

C. Michel et al., "Atomic Structures of Two Rhombohedral Ferroelectric Phases in the Pb(Zr, Ti)O₃ Solid Solution Series," Solid State Communications, Elsevier, Jan 1969.

The definitive version is available at https://doi.org/10.1016/0038-1098(69)90429-3

Department(s)

Physics

Second Department

Chemistry

International Standard Serial Number (ISSN)

0038-1098

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1969 Elsevier, All rights reserved.

Publication Date

01 Jan 1969