Title

Atomic Structures of Two Rhombohedral Ferroelectric Phases in the Pb(Zr, Ti)O₃ Solid Solution Series

Abstract

The atomic positions in perovskitic PbZrxTi1-xO3 were determined for x = 0.9 and x = 0.58, using X-ray and neutron diffraction. The space group is R3c for x = 0.9, the unit cell containing two formula units of the compound, and R3m for x = 0.58, the unit cell containing one formula unit. A linear relationship is found between the displacements of the two cations in isomorphous ferroelectric of the R3c space group. © 1969.

Department(s)

Physics

Second Department

Chemistry

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1969 Elsevier, All rights reserved.

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