Atomic Structures of Two Rhombohedral Ferroelectric Phases in the Pb(Zr, Ti)O₃ Solid Solution Series
The atomic positions in perovskitic PbZrxTi1-xO3 were determined for x = 0.9 and x = 0.58, using X-ray and neutron diffraction. The space group is R3c for x = 0.9, the unit cell containing two formula units of the compound, and R3m for x = 0.58, the unit cell containing one formula unit. A linear relationship is found between the displacements of the two cations in isomorphous ferroelectric of the R3c space group. © 1969.
C. Michel et al., "Atomic Structures of Two Rhombohedral Ferroelectric Phases in the Pb(Zr, Ti)O₃ Solid Solution Series," Solid State Communications, Elsevier, Jan 1969.
The definitive version is available at http://dx.doi.org/10.1016/0038-1098(69)90429-3
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© 1969 Elsevier, All rights reserved.