Thermal Stability of Glasses from the Fe₄(P₂O₇)₃-Fe(PO₃)₃ System

Author

Liying Zhang
Luciana Ghussn
Melodie L. Schmitt
Edgar D. Zanotto
Richard K. Brow, Missouri University of Science and TechnologyFollow
Mark E. Schlesinger, Missouri University of Science and TechnologyFollow

Abstract

Iron phosphate glasses with nominal Fe/P compositions between 0.50 and 0.67 were prepared and characterized. The effects of melt conditions and the initial composition on the Fe(II)-content are reported. Characteristic temperatures, including the glass transition temperature and crystallization temperature, were measured by DSC. The stability of melts against crystallization, described by the Angel and Weinberg parameters, generally decreases with increasing O/P and Fe/P ratios. © 2010 Elsevier B.V. All rights reserved.

Recommended Citation

L. Zhang et al., "Thermal Stability of Glasses from the Fe₄(P₂O₇)₃-Fe(PO₃)₃ System," Journal of Non-Crystalline Solids, Elsevier, Jan 2010.

The definitive version is available at https://doi.org/10.1016/j.jnoncrysol.2010.03.044

Department(s)

Materials Science and Engineering

International Standard Serial Number (ISSN)

0022-3093; 1873-4812

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2010 Elsevier, All rights reserved.

Publication Date

01 Jan 2010