Mixed Transport Control in Gas-liquid Metal Reactions
Laughlin, David E.
The calculation of the rate of gas-liquid metal reactions of the typeA(gas) +B(dissolved) =AB(gas) is described, assuming that the rates are controlled by transport. Mixed control is shown to occur in a number of important gas-liquid metal reactions. This leads to slow rates which may be erroneously ascribed to control by a chemical step. The definition of parameters which can be calculated to indicate without ambiguity whether control is mixed or lies in the gas or liquid phases is discussed.
T. DebRoy et al., "Mixed Transport Control in Gas-liquid Metal Reactions," Metallurgical Transactions B, Springer Verlag, Jan 1977.
The definitive version is available at http://dx.doi.org/10.1007/BF02657656
Materials Science and Engineering
Article - Journal
© 1977 Springer Verlag, All rights reserved.