Crystallization Kinetics of Lithia-Silica Glasses: Effect of Composition and Nucleating Agent

Author

C. S. Ray, Missouri University of Science and TechnologyFollow
Wenhai Huang
D. E. Day, Missouri University of Science and TechnologyFollow

Abstract

The kinetics of crystallization of a 25Li₂O · 75SiO₂ (wt%) glass doped with Pt, Cu, Au, TiO₂, and P₂O₅ were studied using nonisothermal techniques. The activation energy, E, and the frequency factor, v, for the overall crystallization process depended directly on the critical cooling rate for the glass formation, R_c, of these glasses. The crystallization kinetics of several other glasses in the lithia·silica system were also studied as a function of composition, critical cooling rate, and liquidus temperature, T_m. E and v for these glasses were more dependent on the liquidus temperature than on R_c.

Recommended Citation

C. S. Ray et al., "Crystallization Kinetics of Lithia-Silica Glasses: Effect of Composition and Nucleating Agent," Journal of the American Ceramic Society, vol. 70, no. 8, pp. 599 - 603, Wiley-Blackwell, Aug 1987.

The definitive version is available at https://doi.org/10.1111/j.1151-2916.1987.tb05714.x

Department(s)

Materials Science and Engineering

Keywords and Phrases

Crystallization Kinetics; Lithia-silica Glasses; Nucleating Agent; Glass

International Standard Serial Number (ISSN)

0002-7820; 1551-2916

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1987 Wiley-Blackwell, All rights reserved.

Publication Date

01 Aug 1987