Thermally Stimulated Currents and Alkali-Ion Motion in Silicate Glasses
The thermally stimulated polarization/depolarization (TSPC/TSDC) current technique is used to investigate alkali-ion motion in silicate glasses. Two TSDC peaks are observed in all these glasses along with the dc conduction current at high temperatures. The low-temperature TSDC peak magnitude is essentially constant, but the second TSDC peak magnitude varies with the type of alkali ion present in these glasses. Based on a proposed model, the two TSDC peaks are interpreted in terms of the localized alkali-ion motion around the nonbridging oxygen ion and through the limited conduction pathways, respectively.
A. K. Agarwal and D. E. Day, "Thermally Stimulated Currents and Alkali-Ion Motion in Silicate Glasses," Journal of the American Ceramic Society, vol. 65, no. 2, pp. 111-117, Wiley-Blackwell, Feb 1982.
The definitive version is available at https://doi.org/10.1111/j.1151-2916.1982.tb10367.x
Materials Science and Engineering
Keywords and Phrases
Ion Motion; Glass
International Standard Serial Number (ISSN)
Article - Journal
© 1982 Wiley-Blackwell, All rights reserved.