Sodium Motion in Phase-Separated Sodium Silicate Glasses

Author

Horst Dieter Jannek
D. E. Day, Missouri University of Science and TechnologyFollow

Abstract

The thermally stimulated polarization and depolarization current (TSPC/TSDC) technique was used to study Na⁺ ion motion in phase-separated silicate glasses containing between 10.3 and 20 mol% Na₂O. Generally, two TSDC peaks and a high-temperature background (HTB) current were observed. The two TSDC peaks were attributed to different types of Na⁺ motion, i.e. a short-range reorientation process and a longer-range translational motion. Changes in the microstructure affected only the size of the larger TSDC peak located at higher temperatures.

Recommended Citation

H. D. Jannek and D. E. Day, "Sodium Motion in Phase-Separated Sodium Silicate Glasses," Journal of the American Ceramic Society, vol. 64, no. 4, pp. 227 - 233, Wiley-Blackwell, Apr 1981.

The definitive version is available at https://doi.org/10.1111/j.1151-2916.1981.tb10274.x

Department(s)

Materials Science and Engineering

Sponsor(s)

National Science Foundation (U.S.)

Comments

Supported by the National Science Foundation under Grant No. DMR-77-13002.

Keywords and Phrases

Glass

International Standard Serial Number (ISSN)

0002-7820; 1551-2916

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 1981 Wiley-Blackwell, All rights reserved.

Publication Date

01 Apr 1981