Title

Palladium(ii) Complexes Containing 2,6-bis(Imino)Pyridines: Synthesis, Characterization, Thermal Study, and Catalytic Activity in Suzuki Reactions

Abstract

A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change δSz.ast;, enthalpy change δH#, and Gibbs free energy change δG# of the thermal decomposition were calculated by means of several methods based on the single heating rate.

Department(s)

Materials Science and Engineering

Keywords and Phrases

Activation energy; Pd(II) complexes; Pyridine-2,6-diimines; Suzuki reaction; Thermal behavior

International Standard Serial Number (ISSN)

15533174

Document Type

Article - Journal

Document Version

Citation

File Type

text

Language(s)

English

Rights

© 2010 Taylor and Francis, All rights reserved.

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